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If so, then as far as the Church is concerned, there was no marriage. A marriage can also be annulled if it has never been consummated: if the couple have not had sex - and sex with a contraceptive doesn't generally count, of course. So we have five possibilities for a divorced Catholic: in all cases assuming that conditions 2-5 above are met. In this case they are in the same position as anyone else who is unmarried.