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Of course, there are many problems with such dating methods, such as parent or daughter substances entering or leaving the rock, as well as daughter product being present at the beginning.
Here I want to concentrate on another source of error, namely, processes that take place within magma chambers.
The general idea is that many different minerals are formed, which differ from one another in composition, even though they come from the same magma.
The mineral makeup of an igneous rock is ultimately determined by the chemical composition of the magma from which it crystallized.
On the upper left branch of this reaction series, olivine, the first mineral to form, Ml] react with the remaining melt to become pyroxene.
This reaction will continue until the last mineral in the series, biotite mica, is formed.
During the last stage of crystallization, after most of the magma has solidified, the remaining melt will form the minerals quartz, muscovite mica, and potassium feldspar.
Although these minerals crystallize in the order shown, this sequence is not a true reaction series.
In these instances, the feldspar crystals will have calcium-rich interiors surrounded by zones that are progressively richer in sodium.This left branch is called a discontinuous reaction series because each mineral has a different crystalline structure.Recall that olivine is composed of a single tetrahedra and that the other minerals in this sequence are composed of single chains, double chains, and sheet structures, respectively.Lava erupting earlier would come from the top of the magma chamber, and lava erupting later would come from lower down.A number of processes could cause the parent substance to be depleted at the top of the magma chamber, or the daughter product to be enriched, both of which would cause the lava erupting earlier to appear very old according to radiometric dating, and lava erupting later to appear younger.